ONE WEEK COURSE IN THE

 

PRACTICAL DESIGN AND PRODUCTION OF OPTICAL THIN FILMS

 

2012

 

Why This Course/Objective

 

Advanced optical thin films are being used increasingly in communications, optical systems, and light control and collection applications.  The sophistication of the optical coating industry is advancing rapidly to meet ever increasing demands for performance and production capability.  New viewpoints, equipment, and processes are available to support advanced capability and efficiency.  Objectives of this course include: to provide increased knowledge and understanding of the many practical aspects of optical coating design and production, to give hands-on design experience in the techniques and principles discussed, and to elucidate techniques and processes that are commonly successful in meeting optical coating needs.

 

Benefits for You

 

This course will enable you to:

*firmly grasp, visualize, and use design principles and graphical methods in thin film design

*gain hands on computer aided design experience in applying the concepts of this course

*understand Fourier thin film synthesis and compare rugate and discrete layer designs

*estimate what can be achieved before starting a design

*solve practical coating design problems in class

*select appropriate optical coating equipment to support the needed processes

*be familiar with the properties and process know-how for common optical coating materials

*learn about DOE process development techniques and the use of various ion/plasma sources

*understand various monitoring and control strategies and their advantages and limitations

 

Valuable Take-home Materials

 

Mr. Willey's books the Practical Design of Optical Thin Films and Practical Production of Optical Thin Films and software for special calculations and graphics will be provided along with supplementary class notes, and the free version of the internationally used FilmStar design and evaluation software by Fred Goldstein. These can be valuable for future reference.

 

 

Who Should Attend, Who Will Benefit

 

The course is intended to be valuable to new coating engineers, scientists, technical managers, and technicians as well as seasoned thin film scientists who are involved in design, development, and production of optical thin films.  Basic principles are laid out from the beginning for those new to the field, but the evolution of the topics then moves into material and techniques useful to even the more experienced practitioners.  No extensive background in mathematics or physics is required; extensive graphical illustrations are used.

Course Instructor

 

Ron Willey is a consultant with over 40 years in the fields of thin film and optical system design, development, and production.  He is a graduate of MIT in optical instrumentation and has an MS in computer science from FIT.  He has lead groups in optical coating and instrumentation development and production at Martin Marietta, Raytheon, Opto_Mechanik, and LexaLite International.  He is very experienced in practical thin films design, process development, and the application of industrial Design Of Experiment methodology (DOE).  He holds four patents and has published many papers on optical coating, optical design, and economics of optical tolerances.  He is a Fellow of the SPIE and the Optical Society of America.

 

 

Course Outline

 

(Taken directly from the Table of Contents of the Two Books used in the Course.)

 

MONDAY

 

 

Fundamentals of Thin Film Optics     1

1.1.  INTRODUCTION         1

1.2.  REVIEW OF THIN FILM OPTICS PRINCIPLES     5

1.3.  REFLECTANCE DIAGRAMS AND DESIGN          12

1.3.1.  Low Reflectors, Antireflection Coatings        15

1.3.2.  Physical Thickness versus Optical Thickness   22

1.3.3.  Three-Layer AR Coating on Germanium, Example    22

1.3.4.  Example Four-Layer Broad Band AR Coating in the Visible 26

1.3.5.  Behavior of a High Index Slab            27

1.3.6.  High Reflectors            29

1.3.7.  Beamsplitters   36

1.3.8.  Higher Harmonic Reflection Bands    36

1.3.9.  Minus Filters and Narrow Blocking Bands     39

1.3.10.  Another Approach to Narrow Blocking Bands         41

1.3.11.  Fencepost and Posthole Design Approaches 42

1.4.  APPROXIMATIONS OF INDICES AND DESIGNS            46

1.4.1.  Herpin/Epstein Periods            46

1.4.2.  More General Approximations            48

1.5.  INHOMOGENEOUS INDEX FUNCTIONS  51

1.5.1.  Step-Down Functions  52

1.5.2.  Low Index Limitations            59

1.5.3.  Lithographic “Moth-Eye” ARs            61

1.5.4.  Overcoming Low Index Limitations With Thickness 63

1.5.5.  Additional Thickness Functions          63

1.5.6.  A Fourier Approach     69

1.5.7.  Rugates and the EUV/Soft X-ray Spectral Region     74

1.5.8.  Potential Quantization Effects in Designs for EUV Mirrors   86

1.6  ANGLES AND POLARIZATION        92

1.6.1.  Wavelength Shift with Angle of Incidence     92

1.6.2.  Polarization Effects of Angle of Incidence     93

1.6.3.  Polarization as Seen in Reflectance Amplitude Diagrams       96

1.6.4.  Polarizing Beamsplitters          99

1.6.5.  Non-Polarizing Beamsplitters  102

1.7.  ADDITIONAL VIEWS VIA GRAPHICS AND PLOTS       106

1.7.1.  Admittance Diagrams  106

1.7.2.  Ellipsometry Plots        109

1.7.3.  Additional Graphics for Visualization 117

1.8.  TRIANGLE DIAGRAMS AND DESIGN      118

1.8.1.  Designing Coatings with Absorbing Materials            121

1.8.2.  Induced Transmission Filter Example 131

1.8.3.  NBP Reflection Filter Example           134

1.8.4.  AR Coated Variable Neutral Density Filter Example 137

1.8.5.  Conclusions of Designing With Metals           142

1.9.  NARROW BANDPASS FILTERS      142

1.9.1.  NBP Wavelength Effects as Seen on Reflectance Diagrams  149

1.9.2.  Dense Wavelength Division Multiplexing (DWDM) Filters   152

1.9.3.  Fiber Bragg Gratings   155

1.10.   FENCEPOST DESIGN EXAMPLES            155

1.10.1.  Edge Filters    158

1.10.2.  Fencepost Narrow Bandpass Filters  160

1.11.  OPTIMIZATION         163

1.11.1.  Performance Goals and Weightings  164

1.11.2.  Global versus Local Minima  165

1.11.3.  Some Optimizing Concepts   166

1.11.4.  Constraints     171

1.11.5.  Quantization  173

1.12.  SUMMARY     175

1.13.  REFERENCES            176

 

TUESDAY

 

Estimating What Can Be Done Before Designing     181

2.1.  INTRODUCTION         181

2.2.  ANTIREFLECTION COATINGS        181

2.2.1.  Procedure         182

2.2.2.  The Formula     183

2.2.3.  Results 185

2.2.4.  Berlin AR Design Contest       189

2.2.5.  Results of Further Study         191

2.2.6.  Estimating the Number of Layers        197

2.2.7.  Looking Outside the Box        199

2.2.8.  Reverse Engineering Using Number of Ripples in Band        203

2.3.  BANDPASS AND BLOCKER COATINGS   204

2.3.1.  Estimating the Width of a Blocking Band      204

2.3.2.  Estimating the Optical Density of a Blocking Band   206

2.3.3.  Estimating the Number of Layers and Thickness Needed      207

2.3.4.  Estimating More Complex Coatings    208

2.3.5.  Estimating Edge Filter Passband Reflection Losses   214

2.4.  DICHROIC REFLECTION COATINGS        223

2.5.  DWDM FILTERS          225

2.6.  ESTIMATING OD AND BW OF FENCEPOSTS       230

2.7.  SUMMARY       233

Fourier Viewpoint of Optical Coatings          237

3.1.  INTRODUCTION         237

3.2.  FOURIER CONCEPTS 237

3.2.1.  Background     239

3.2.2.  Some Limitations         247

3.2.3.  A Method to Determine the Multiple Reflections       253

3.3.  SUMMARY       255

3.4.  REFERENCES  256

AR Coating Design Example 279

C.1.  DESIGNING A VBBAR         279

C.2.  OTHER EXAMPLES   291

C.3.  REFERENCES  294

Color Measurement, Introduction      297

D.1.  WHAT IS COLOR MEASUREMENT?          297

D.2.  REFERENCES 303

 

 

WEDNESDAY

 

 

Typical Equipment for Optical Coating Production   1

1.1.  INTRODUCTION         1

1.2.  GENERAL REQUIREMENTS            2

1.2.1.  The Vacuum     4

1.2.2.  Deposition Sources      20

1.2.3.  Fixturing and Uniformity        48

1.2.4.  Temperature Control    58

1.2.5.  Process Control            62

1.3.  TYPICAL EQUIPMENT          64

1.4.  ALTERNATIVE APPROACHES        68

1.5.  UTILITIES         68

1.6.  REFERENCES  73

Materials and Processes          81

2.1.   INTRODUCTION        81

X.X.  SPECTROPHOTOMETERS

X.X.X Monochrometers

X.X.X Double-Beam Photometers

X.X.X Fourier Spectrometers

X.X.X Diffuse Reflectance and Integrating Spheres

X.X.X Measuring Transmittance and Error Sources

X.X.X Calibrating and Measuring Specular Reflectance

X.X.X Angular and Absolute Reflectance

X.X.X An Alternative Optical Coating Spectrometer

Y.Y. COLOR MEASUREMENTS

Y.Y.Y. Some Color Software Tools

Z.Z.  Finding n and k Values

2.1.0.   Measuring Spectral Results in the Real World           81

2.1.1.   Index of Refraction Determination    91

2.2.   PROCESS KNOW-HOW         101

2.2.1.  Film Growth Models and Observations          102

2.2.2.  Chiral and Sculptured Coatings           107

2.2.3.  Stress in Coatings        107

2.2.4.  Laser Damage in Coatings       109

2.2.5.  Rain Erosion of Coatings         112

2.3.   MATERIALS    114

2.3.1.   Some Specific Materials         115

A.A.A. Setting Crystal Controller PID Values

2.4.   ION SOURCES            160

2.4.1.   Cold Cathode Source 161

2.4.2.   End-Hall Source         163

2.4.3.   PS1500 Plasma/Ion Source     166

2.5.   ION/ATOM RATIOS AND IMPLICATIONS           179

2.6.   OTHER PROCESSES TO CONSIDER          183

2.6.1.   Physical Vapor Deposition     184

2.6.2.   Dip, Spin, and Spray Coatings           185

2.6.3.   Chemical Vapor Deposition    185

2.6.4.   Plasma-Enhanced CVD          186

2.6.5.   Plasma Polymerization            186

2.6.6.   Hard Carbon Coatings            187

2.7.   SUMMARY      189

2.8.   REFERENCES 190

 

THURSDAY

 

Thin Film Monitoring and Control     249

4.1 Effects of Errors   252

4.2 Ways to Monitor   256

4.2.1.  "Eyeball" and Measured Charge          258

4.2.2.  Time-Power/Rate Monitoring  261

4.2.3.  Crystal Monitoring       261

4.2.4.  Optical Thickness Monitors     264

4.2.5.  Trade-offs in Monitoring         278

4.3 Error Compensation and Degree of Control         279

4.3.1.  Narrow Bandpass Filter Monitoring    280

4.3.2.  DWDM Filter Monitoring       285

4.3.3  Error Compensation in Edge Filters     308

4.3.4.  Broad Band Monitoring Compensation          309

4.3.5.  Effects of Thin Film Wedge on the Monitor Chip      310

4.3.6.  Error Due to Width of the Monitoring Passband        312

4.4 Calibrations and Variations          314

4.4.1.  Tooling Factors            315

4.4.2.  Variations         316

4.4.3.  The Optical Monitor with Crystal Method of Schroedter       317

4.4.4.  Suggestion for Computer Aided Monitoring of DWDM Filters         319

4.5 Sensitivity and Strategies 320

4.5.1.  Sensitivity versus Layer Termination Point in Reflectance     320

4.5.2.  Sensitivity Versus g-Value      322

4.5.3.  Precoated Monitor Chips         325

4.5.4.  Eliminating the Precoated Chip           326

4.5.5.  Constant Level Monitoring Strategies 333

4.5.6.  Steering the Monitoring Signal Result 338

4.5.7.  Variation of Band-Edge Position with Monitoring Errors      346

4.5.8.  Almost Achromatic Absentee Layers  355

4.6 Practical Considerations   358

4.6.1.  A Narrow Bandpass Filter       358

4.6.2.  A Special "Multichroic" Beamsplitter  359

4.6.3.  A Very Broadband Antireflection Coating     361

4.6.4.  Intermittent Monitoring           367

4.6.5  Single Beam versus Double Beam Optical Monitors    368

4.6.6.  Automation versus Manual Monitoring           369

4.7 Fencepost Monitoring       371

4.8 Monitoring Non-QWOT NBP Filters       376

4.9 Summary   389

4.10 References          391

 

Banquet (Included in Course Fee)

 

 

FRIDAY

 

Process Development  219

3.1.   INTRODUCTION        219

3.2.   DESIGN OF EXPERIMENTS METHODOLOGY    223

3.2.1.   Process Flow Diagram            223

3.2.2.   Cause-and-Effect Diagram     224

3.2.3.   Control, Noise, or Experiment            224

3.2.4.   Standard Operating Procedures          226

3.3.   DESIGN OF THE EXPERIMENTS: EXAMPLES    226

3.3.1.   A Central Composite Design for Aluminizing           227

3.3.2.   A Box-Behnken Design for IAD Deposition of TiO2           231

3.4.   A REAL LIFE EXAMPLE OF PROBLEM SOLVING         238

3.5.   SUMMARY      248

3.6.   REFERENCES 248

 

Note: The order of presentations may be changed without notice.

 

(Updated 8-12-11)